Critical Acclaim for Enrico Fermi: "He was simply unable to let things be foggy.
Since they always are, this kept him pretty active. Robert Oppenheimer. Enrico Fermi. Indisputably, this is a modern classic of science. Based on a course of lectures delivered by the author at Columbia University, the text is elementary in treatment and remarkable for its clarity and organization. Although it is assumed that the reader is familiar with the fundamental facts of thermometry and calorimetry, no advanced mathematics beyond calculus is assumed.
Partial contents: thermodynamic systems, the first law of thermodynamics application, adiabatic transformations , the second law of thermodynamics Carnot cycle, absolute thermodynamic temperature, thermal engines , the entropy properties of cycles, entropy of a system whose states can be represented on a V, p diagram, Clapeyron and Van der Waals equations , thermodynamic potentials free energy, thermodynamic potential at constant pressure, the phase rule, thermodynamics of the reversible electric cell , gaseous reactions chemical equilibria in gases, Van't Hoff reaction box, another proof of the equation of gaseous equilibria, principle of Le Chatelier , the thermodynamics of dilute solutions osmotic pressure, chemical equilibria in solutions, the distribution of a solute between 2 phases vapor pressure, boiling and freezing points , the entropy constant Nernst's theorem, thermal ionization of a gas, thermionic effect, etc.
This principle, as noted by James Maxwell in , asserts that it is possible to measure temperature. An idealized thermometer is a sample of an ideal gas at constant pressure. Although pressure is defined mechanically, a pressure-measuring device, called a barometer may also be constructed from a sample of an ideal gas held at a constant temperature.
A calorimeter is a device which is used to measure and define the internal energy of a system. A thermodynamic reservoir is a system which is so large that its state parameters are not appreciably altered when it is brought into contact with the system of interest. When the reservoir is brought into contact with the system, the system is brought into equilibrium with the reservoir. For example, a pressure reservoir is a system at a particular pressure, which imposes that pressure upon the system to which it is mechanically connected.
The Earth's atmosphere is often used as a pressure reservoir. If ocean water is used to cool a power plant, the ocean is often a temperature reservoir in the analysis of the power plant cycle. The central concept of thermodynamics is that of energy , the ability to do work. By the First Law , the total energy of a system and its surroundings is conserved.
Energy may be transferred into a system by heating, compression, or addition of matter, and extracted from a system by cooling, expansion, or extraction of matter. In mechanics , for example, energy transfer equals the product of the force applied to a body and the resulting displacement. Conjugate variables are pairs of thermodynamic concepts, with the first being akin to a "force" applied to some thermodynamic system , the second being akin to the resulting "displacement," and the product of the two equalling the amount of energy transferred. The common conjugate variables are:.
Thermodynamic potentials are different quantitative measures of the stored energy in a system. Potentials are used to measure the energy changes in systems as they evolve from an initial state to a final state. The potential used depends on the constraints of the system, such as constant temperature or pressure. For example, the Helmholtz and Gibbs energies are the energies available in a system to do useful work when the temperature and volume or the pressure and temperature are fixed, respectively.
Thermodynamic potentials can be derived from the energy balance equation applied to a thermodynamic system. Other thermodynamic potentials can also be obtained through Legendre transformation. From Wikipedia, the free encyclopedia. The classical Carnot heat engine. Classical Statistical Chemical Quantum thermodynamics. Zeroth First Second Third.
System properties. Note: Conjugate variables in italics.
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Physics portal. The opposite sign convention is customary in chemical thermodynamics. Mathematical and Physical Papers. London, Cambridge: C. Clay, M. Transactions of the Connecticut Academy of Arts and Sciences. New Haven. Thermodynamics and the Free Energy of Chemical Substances.
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